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Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

《环境科学与工程前沿（英文）》 2019年第13卷第5期 doi: 10.1007/s11783-019-1152-1

摘要： The wastewater from industrial area was treated by EC via Fe and Al electrodes. Cu, Ni, Cr and Zn were highly removed at the first minutes, simultaneously. Pseudo-2nd-order was found to be more suitable for kinetics. Adsorption capacities based on kinetic modeling were observed as Cr>Cu>Ni>Zn. The chemical cost in the case of pH adjustment after EC was less as 3.83 $/m3. It is known that wastewater produced by the metal-plating industry contains several heavy metals, which are acidic in nature and therefore toxic for the environment and for living creatures. In particular, heavy metals enter the food chain and accumulate in vital organs and cause serious illness. The precipitation of these metals is mostly achieved by pH adjustment, but as an alternative to this method, the electrocoagulation process has investigated in this study using iron and aluminum electrodes. The effects of the pH adjustment on removal before and after the electrocoagulation process were investigated, and cost analyses were also compared. It was observed that a high proportion of removal was obtained during the first minutes of the electrocoagulation process; thus, the current density did not have a great effect. In addition, the pH adjustment after the electrocoagulation process using iron electrodes, which are 10% more effective than aluminum electrodes, was found to be much more efficient than before the electrocoagulation process. In the process where kinetic modeling was applied, it was observed that the heavy metal removal mechanism was not solely due to the collapse of heavy metals at high pH values, and with this modeling, it was seen that this mechanism involved adsorption by iron and aluminum hydroxides formed during the electrocoagulation process. When comparing the ability of heavy metals to be adsorbed, the sequence was observed to be Cr>Cu>Ni>Zn, respectively.

关键词： Electrochemical treatment Heavy metals Kinetic modeling Pseudo first order kinetic Pseudo second order kinetic

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Kinetic energy based model assessment and sensitivity analysis of vortex induced vibration of segmental

Nazim Abdul NARIMAN

《结构与土木工程前沿（英文）》 2017年第11卷第4期页码 480-501 doi: 10.1007/s11709-017-0435-5

摘要： In this paper, semi 3D models for segmental Bridge decks are created in ABAQUS CFD program with the support of MATLAB codes to simulate and analyze vortex shedding generated due to wind excitation through considering the stationary position of the deck. Three parameters (wind speed, deck streamlined length and dynamic viscosity of the air) are dedicated to study their effects on the kinetic energy of the system in addition to the shapes and patterns of the vortices. Two benchmarks from the literature Von Karman and Dyrbye and Hansen are considered to validate the vortex shedding aspects for the CFD models. Good agreement between the results of the benchmarks and the semi 3D models has been detected. Latin hypercube experimental method is dedicated to generate the surrogate models for the kinetic energy of the system and the lift forces. Variance based sensitivity analysis is utilized to calculate the main sensitivity indices and the interaction orders for all the three parameters. The kinetic energy approach performed very well in revealing the rational effects and the roles of each parameter in the generation of vortex shedding and predicting vortex induced vibration of the deck.

关键词： vortex induced vibration reynolds number kinetic energy vorticity latin hypercube sampling

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for damage detection in functionally graded carbon nanotube-reinforced composite plates using modal kineticenergy

《结构与土木工程前沿（英文）》 2021年第15卷第6期页码 1453-1479 doi: 10.1007/s11709-021-0767-z

摘要： This paper proposes a new Deep Feed-forward Neural Network (DFNN) approach for damage detection in functionally graded carbon nanotube-reinforced composite (FG-CNTRC) plates. In the proposed approach, the DFNN model is developed based on a data set containing 20 000 samples of damage scenarios, obtained via finite element (FE) simulation, of the FG-CNTRC plates. The elemental modal kinetic energy (MKE) values, calculated from natural frequencies and translational nodal displacements of the structures, are utilized as input of the DFNN model while the damage locations and corresponding severities are considered as output. The state-of-the art Exponential Linear Units (ELU) activation function and the Adamax algorithm are employed to train the DFNN model. Additionally, in order to enhance the performance of the DFNN model, the mini-batch and early-stopping techniques are applied to the training process. A trial-and-error procedure is implemented to determine suitable parameters of the network such as the number of hidden layers and the number of neurons in each layer. The accuracy and capability of the proposed DFNN model are illustrated through two distinct configurations of the CNT-fibers constituting the FG-CNTRC plates including uniform distribution (UD) and functionally graded-V distribution (FG-VD). Furthermore, the performance and stability of the DFNN model with the consideration of noise effects on the input data are also investigated. Obtained results indicate that the proposed DFNN model is able to give sufficiently accurate damage detection outcomes for the FG-CNTRC plates for both cases of noise-free and noise-influenced data.

关键词： damage detection deep feed-forward neural networks functionally graded carbon nanotube-reinforced composite plates modal kinetic energy

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系统的稳定性与不稳定性——搅动能守恒律意义和作用的引伸性讨论

陈刚毅,欧阳伯嶙,袁东升,郝丽萍,周莉蓉

《中国工程科学》 2005年第7卷第8期页码 41-46

摘要：

讨论了欧阳首承提出的搅动能守恒律意义和作用，并结合曲率空间做了引伸性的讨论，认为搅动能守恒定律是系统稳定性和演化分析的重要原理和方法，它既是解释系统稳定性的原因，也可以作为系统演化分析的方法，并指出了牛顿体系的某些本质性问题。

关键词：系统结构搅动能稳定性与演化性

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减灾、防灾与“给能量留有空间”的对策问题

陈刚毅,陆雅君

《中国工程科学》 2011年第13卷第3期页码 92-96

摘要：

根据欧阳首承提出的“搅动能守恒定律”揭示的能量不能脱离物质，而必须给能量留有空间的理论，论述了能量空间与自然灾害和灾变动力的相互关系和作用，给出了能量空间在灾后重建工程、防洪减灾规划和生态环境规划等的应用和对策。并强调自然灾害、人为建筑工程“必须给能量留有空间”，才能更为有效地防灾、减灾。提出了“给能量留有空间”是针对当代科学遗漏了能量空间问题提出的新的科学命题。

关键词：搅动能守恒能量空间防灾减灾灾后重建

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Reaction kinetics of CaC

Renxing Wang,Zhenyu Liu,Leiming Ji,Xiaojin Guo,Xi Lin,Junfei Wu,Qingya Liu

《化学科学与工程前沿（英文）》 2016年第10卷第4期页码 517-525 doi: 10.1007/s11705-016-1585-z

摘要： The production of CaC from coke/lime powders and compressed powder pellets are low cost and fast processes. A number of studies have reported the reaction kinetics of these reactions but they are still not well understood and the proposed kinetic models are not comparable due to differences in the reaction conditions. Therefore the reaction behavior of CaO/C powders (0.074 mm) and cubes (5 mm × 5 mm × (4.6–5.1) mm) compressed from a mixture of powders have been studied using thermal gravimetric analysis (TGA) at 1700– 1850 °C. Kinetic models were obtained from the TGA data using isoconversional and model-fitting methods. The reaction rates for the compressed feeds were lower than those for the powder feeds. This is due to the reduced surface area of the compressed samples which inhibits heat transfer from the surrounding environment (or the heating source) to the sample. The compression pressure had little influence on the reaction rate. The reaction kinetics of both the powder and the compressed feeds can be described by the contracting volume model ( ) = 3(1− ) , where is the conversion rate of reactant. The apparent activation energy and pre-exponential factor of the powder feed were estimated to 346–354 kJ?mol and 5.9 × 10 min , respectively, whereas those of the compressed feed were 305–327 kJ?mol and 3.6 × 10 min , respectively.

关键词： calcium carbide kinetic model activation energy pre-exponential factor

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Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

《能源前沿（英文）》 2015年第9卷第2期页码 125-133 doi: 10.1007/s11708-015-0346-x

摘要： The thermal behavior of combustion in air atmosphere were investigated by performing experiments on STA PT1600 Thermal Analyzer at heating rates of 10°C/min, 40°C/min and 70°C/min and range of temperatures from room temperature to 1200°C. The kinetic parameters were evaluated by using Kissinger and Ozawa methods. The result showed that combustion occurred in five stages. Started with initial devolatilization, the main thermal decomposition and combustion process, transition stage, the combustion of char and the last stage was the slow burning reaction of residual char. In line with increasing heating rate, the mass loss rate increased as well, but it delayed the thermal decomposition processes toward higher temperatures. The average activation energy at the main thermal decomposition stage and the stage of char combustion were approximately 251 kJ/mol and 178 kJ/mol, respectively.

关键词： Nannochloropsis oculata combustion kinetic parameters air atmosphere thermogravimetric

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

《能源前沿（英文）》 2022年第16卷第2期页码 263-276 doi: 10.1007/s11708-021-0791-7

摘要： The laminar flame speeds of ammonia mixed with syngas at a high pressure, temperature, and different syngas ratios were measured. The data obtained were fitted at different pressures, temperatures, syngas ratios, and equivalence ratios. Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared and validated with experimental data. Pathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on ammonia oxidation and NO formation. The pathway analysis shows that H abstraction reactions and NH_i combination reactions play important roles in ammonia oxidation. NO formation is closely related to H, OH, the O radical produced, and formation reactions. NO is mainly formed from reaction, HNO+ H= NO+ H₂. Furthermore, both ammonia oxidation and NO formation are sensitive to small radical reactions and ammonia related reactions.

关键词： ammonia mixed with syngas laminar flame speed kinetic model sensitivity analysis pathway analysis

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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

《化学科学与工程前沿（英文）》 2013年第7卷第2期页码 139-144 doi: 10.1007/s11705-013-1323-8

摘要： Coker gas oil (CGO) is a poor-quality feedstock for fluidized bed catalytic cracking (FCC) or hydrocracking. The pretreatment of CGO, especially hydrotreating, can significantly improve the product quality and protect the catalyst. In this work, we studied the hydrodesulfurization (HDS) of CGO in a slurry reactor. All the experiments were carried out in an autoclave using a NiMo/Al O catalyst at reaction temperature 340°C–400°C, pressure 6–10 MPa, and stirring speed 800 r·min , with hydrogen-to-oil ratio in the range of 500–1500. The effects of the operating parameters on the desulfurization ratio were investigated and discussed. A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

关键词： coker gas oil hydrodesulfurization slurry reactor reaction kinetic model

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photoreduction process in a laboratory-scale photoreactor by computational fluid dynamic and reaction kinetic

《化学科学与工程前沿（英文）》 2022年第16卷第7期页码 1149-1163 doi: 10.1007/s11705-021-2096-0

摘要： The production of solar fuels via the photoreduction of carbon dioxide to methane by titanium oxide is a promising process to control greenhouse gas emissions and provide alternative renewable fuels. Although several reaction mechanisms have been proposed, the detailed steps are still ambiguous, and the limiting factors are not well defined. To improve our understanding of the mechanisms of carbon dioxide photoreduction, a multiphysics model was developed using COMSOL. The novelty of this work is the computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kinetic model, which was built based on three-steps, namely gas adsorption, surface reactions and desorption, while the ultraviolet light intensity distribution was simulated by the Gaussian distribution model and Beer-Lambert model. The carbon dioxide photoreduction process conducted in a laboratory-scale reactor under different carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic model. It was found that the simulation results for methane, carbon monoxide and hydrogen yield match the experiments in the concentration range of 10⁻⁴ mol·m^–3 at the low carbon dioxide and water moisture partial pressure. Finally, the factors of adsorption site concentration, adsorption equilibrium constant, ultraviolet light intensity and temperature were evaluated.

关键词： carbon dioxide photoreduction computational fluid dynamic simulation kinetic model Langmuir adsorption

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Kinetic study of the methanol to olefin process on a SAPO-34 catalyst

Mehdi SEDIGHI,Kamyar KEYVANLOO

《化学科学与工程前沿（英文）》 2014年第8卷第3期页码 306-311 doi: 10.1007/s11705-014-1440-z

摘要： In this paper, a new kinetic model for methanol to olefin process over SAPO-34 catalyst was developed using elementary step level. The kinetic model fits well to the experimental data obtained in a fixed bed reactor. Using this kinetic model, the effect of the most important operating conditions such as temperature, pressure and methanol space-time on the product distribution has been examined. It is shown that the temperature ranges between 400 °C and 450 °C is appropriate for propene production while the medium temperature (450 °C) is favorable for total olefin yield which is equal to 33%. Increasing the reactor pressure decreases the ethylene yield, while medium pressure is favorable for the propylene yield. The result shows that the ethylene and propylene and consequently the yield of total olefins increase to approximately 35% with decreasing the molar ratio of inlet water to methanol.

关键词： methanol to olefin SAPO-34 kinetic modeling elementary step

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Application of micro-genetic algorithm for calibration of kinetic parameters in HCCI engine combustion

HUANG Haozhong, SU Wanhua

《能源前沿（英文）》 2008年第2卷第1期页码 86-92 doi: 10.1007/s11708-008-0003-8

摘要： The micro-genetic algorithm (?GA) as a highly effective optimization method, is applied to calibrate to a newly developed reduced chemical kinetic model (40 species and 62 reactions) for the homogeneous charge compression ignition (HCCI) combustion of -heptane to improve its autoignition predictions for different engine operating conditions. The seven kinetic parameters of the calibrated model are determined using a combination of the Micro-Genetic Algorithm and the SENKIN program of CHEMKIN chemical kinetics software package. Simulation results show that the autoignition predictions of the calibrated model agree better with those of the detailed chemical kinetic model (544 species and 2 446 reactions) than the original model over the range of equivalence ratios from 0.1–1.3 and temperature from 300–3 000 K. The results of this study have demonstrated that the mGA is an effective tool to facilitate the calibration of a large number of kinetic parameters in a reduced kinetic model.

关键词： homogeneous different combustion autoignition compression

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Influence of fluid-structure interaction on vortex induced vibration and lock-in phenomena in long span bridges

Nazim Abdul NARIMAN

《结构与土木工程前沿（英文）》 2016年第10卷第4期页码 363-384 doi: 10.1007/s11709-016-0353-y

摘要： In this paper, deck models of a cable stayed bridge are generated in ABAQUS-finite element program once using only CFD model (one-way fluid-structure interaction) and another by using both the CFD model and the CSD model together (two-way fluid-structure interaction) in a co-simulation. Shedding frequencies for the associated wind velocities in the lock-in region are calculated in both approaches. The results are validated with Simiu and Scanlan results. The lift and drag coefficients are determined for the two approaches and the latter results are validated with the flat plate theory results by Munson and coauthors. A decrease in the critical wind velocity and the shedding frequencies considering two-way approach was determined compared to those obtained in the one-way approach. The results of the lift and drag forces in the two-way approach showed appreciable decrease in their values. It was concluded that the two-way approach predicts earlier vortex induced vibration for lower critical wind velocities and lock-in phenomena will appear at lower natural frequencies of the long span bridges. This helps the designers to efficiently plan and consider for the design and safety of the long span bridge against this type of vibration.

关键词： vortex-induced vibration fluid-structure interaction Strouhal number lock-in kinetic energy